Showing posts with label theoretical chemistry. Show all posts
Showing posts with label theoretical chemistry. Show all posts

3/01/2013

Quantum Chemistry: A Unified Approach Review

Quantum Chemistry: A Unified Approach
Average Reviews:

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This book is a valuable guide for people who are interested in quantum chemistry, especially for first year students. It is also a good textbook for an educator in quantum chemistry

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This book is a presentation of a qualitative theory of chemical bonding stressing the physical processes which occur on bond formation. It differs from most (if not all) other books in that it does not seek to 'rationalize' the phenomena of bonding by a series of mnemonic rules. A principal feature is a unified and consistent treatment across all types of bonding in organic, physical and inorganic chemistry.
Contents: How Science Deals with Complex Problems; What We Know About Atomsand Molecules; A Strategy for Electronic Structure; The Pauli Principle andOrbitals; A Model Polyatomic: Methane; Lone Pairs of Electrons; OrganicMolecules with Multiple Bonds; Molecular Symmetry; Diatomics with MultipleBonds; Dative Bonds; Delocalised Electronic Substructures: Aromaticity;Organic and Inorganic Chemistry; Further Down the Periodic Table;Reconsidering Empirical Rules; Mavericks and Other Lawbreakers; The TransitionElements; Omissions and Conclusions.

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1/09/2013

Quantum Many-particle Systems (Advanced Books Classics) Review

Quantum Many-particle Systems (Advanced Books Classics)
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A great physics book for field theory applied to condensed
matter and sometimes nuclear physics problems. The authors
are EXTREMELY careful mathematically and really don't skip
any steps or shove stuff under the rug; in fact, the first
chapter is just all math about how to do integrals and path
integrals and field integrals and deal with Grassman numbers.
A bit unusual for a physics book, but that's their style.
The rest of the book deals with the usual and other material:
zero-temperature Green's functions and perturbation theory
(for energy, Green's function, etc.) The treatment is detailed
and relatively exhaustive. Then there is the same for finite-
temperature. The earlier sections on linear response are
concise and one of the best treatments of the subject I have
seen leading directly to the fluctuation dissipation expression
(after this book I realized this vaunted "fluctuation-dissipation" that no one can explain is just
a straightforward thing about commutators and pert. theory).
The book also has other good stuff: a chapter on mean field theory, Landau-Ginzburg theory, order parameters, and a nice
discussion about spontaneous symmetry breaking that helps
clarify a bunch of stuff. Then there is a whole chapter on
further aspects of one-particle Green's functions (Dyson
equation, solving for poles, quasiparticles, satellites, etc.)
that is pretty good and gets the physical point across. There
is also a chapter on statistical (monte carlo, numerical, etc.)
methods for doing quantum many body problems. While some of
the methods are not the most up to date or modern, the basics
are all there (Monte Carlo, Hubbard-Strataonvich (spelling?),
inverting matrices via Monte Carlo, some stuff about lattice
systems, Langevin equation simulation for Monte Carlo, updating
problems, etc.) There is also a chapter on more advanced
functional integration stuff. Also there is a nice description
of the loop expansion and whatnot.
The book is very well written, has no errors as far as I can
tell, and is exhaustive on what it treats. The problems at
the end of the first few chapters deal with physics problems
and help build intuition whereas the texts in these chapters
are more formal. The book could use some more physical insights
sprinkled throughout, but that is not too much of a drawback.
The book is based on functional integration (Feynman integral)
methods for field theory: this is the modern way folks do it
and it is a powerful way of doing field theory both to
derive results, connect results, do expansions and what not,
and also for certain kinds of monte carl computations. So
having read this, the reader is up to date on a pretty modern
view of field theory in condensed matter (and somewhat on
nuclear physics).
Highly recommended unless you can't stand precise and long
mathematical treatments. My only misgiving is that sometimes
I wish the authors provided more physical insights for certain
concepts and gave some examples rather than "just the math";
but they do this in other parts of the book, so perhaps
my complaint, which is not that serious, is more about the
uneven way this is done. Nevertheless, this is 5/5 and a book
you will read many times and learn from many times.

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This book explains the fundamental concepts and theoretical techniques used to understand the properties of quantum systems having large numbers of degrees of freedom. A number of complimentary approaches are developed, including perturbation theory; nonperturbative approximations based on functional integrals; general arguments based on order parameters, symmetry, and Fermi liquid theory; and stochastic methods.

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